Journal of Microwave Power
and Electromagnetic Energy (JMPEE) |
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TITLE |
A Study of Experimental and
Theoretical Shifts in a Resonant Microwave Cavity Loaded with Polar and
Non-Polar Molecules in Gas Phase [PDF] |
AUTHORS |
G. Joni,
R. Ngoui and J. Roberts 1989 24 4 227-235 |
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Abstract Shifts in the cavity resonance
at microwave frequencies 9.034 and 18.068 GHz, at low pressures and at room
temperature, have been measured using a microwave cavity technique. Various
linear, diatomic, symmetric and asymmetric polar,
and non polar molecules were chosen for perturbation of the cavity. The data
are analyzed using a new alternative relation for dipole-dipole, and quadrupole-quadrupole interactions. The theoretical
representation satisfactorily explains the observed shifts. The gas phase
dielectric permittivities are also derived. Key Words: Dielectric measurement,
Intermolecular forces, Dielectric properties, Microwave cavity perturbations,
Electrical measurements and techniques. |