Journal of Microwave Power
and Electromagnetic Energy (JMPEE) |
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TITLE |
Microwave Athermal Effects in Chemistry: A Myth’s Autopsy – Pat I: Historial background and fundamentals of wave-matter
interaction [PDF] |
AUTHORS |
D.A.C.
Stuerga and P. Gaillard 1996 31 2 87-100 |
YEAR |
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VOLUME |
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ISSUE |
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PAGES |
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Abstract The purpose of this paper
is to enlighten by a theoretical analysis the controversial question of athermal, specific or molecular effects of microwave
heating claimed in chemistry. In this Part I, thermodynamic considerations
relating to transition state theories are reviewed. The different assumptions
of specific effects claimed in chemistry are examined, and a
brief overview of biological effects of electromagnetic irradiation are
reported. Chemical experiments which claim athermal
effects then are analyzed. Finally, fundamentals of wave matter interaction
are given. Key Words: Specific effects, Athermal effects, Bioeffects,
Reaction rate enhancement, Wave-matter interaction. |