Journal of Microwave Power and Electromagnetic Energy (JMPEE)

 

TITLE

Microwave Regeneration of Adsorbents at Low Pressure: Experimental Kinetics Studies [PDF]

AUTHORS

D.W. Price and P.S. Schmidt

1997

32

3

145-154

YEAR

VOLUME

ISSUE

PAGES

 

Abstract

Experimental studies were performed to demonstrate the feasibility of regenerating adsorbents by microwave irradiation to effect recovery of volatile organic compounds (VOCs). Low pressure (sub-ambient) microwave desorption tests were conducted in a 2450 MHz multimode cavity for water, methyl ethyl ketone. toluene, and n-propyl acetate on molecular sieves 5A and 13X, UOP MHSZ, and Dowex Optipore adsorbents. The results show that the dielectrically enhanced mass transfer characteristics result in a system which follows a quasi-equilibrium process consistent with the manufacturer sorption equilibrium data; accordingly, desorption increases with temperature and decreasing system pressure and is not rate-limited by mass transfer resistances.

 

Key Words: Microwave heating, adsorbents, regeneration, desorption, VOC